化工热力学导论（英文改编版）
作 者： （美）史密斯（Smith.J.M.），（美）范内斯（Van Ness,H.C.），（美）阿博特（Abbott,M.M.）著； 出版时间： 2014
内容简介
Smith教授等编著的《化工热力学导论》是世界化工领域影响最大、发行范围最广的化工热力学教材。本书是根据英文原版书《化工热力学导论》第7版改编。改编书选取了原书前13章，内容涵盖了化学工程师专业教育所必需的内容。全书主要内容包括以下几个方面：热力学基本概念和基本定律、纯流体的PVT性质、热效应、纯流体的热力学性质、热力学在流动过程中的应用、热力做功、制冷、汽液平衡、溶液热力学理论和应用以及化学反应平衡。这13章内容可以分为三部分：热力学和化学热力学基础，包括第1-6章；热力学在工业过程中的应用，包括第7-9章；热力学在化学过程中的应用，包括第10-13章。书中给出了大量既有理论意义，又切合工业实际的例题，并配有大量来自工业实践的习题。全书行文流畅、图表丰富、通俗易懂。可作为化学工程与工艺专业以及其他相关专业的化工热力学教科书，也可以作为相关专业研究人员，工程设计和生产管理技术人员的重要参考书，也可以用作化工专业英语的教材或选读材料。
List of Symbols
Preface
Chapter 1 Introduction 1
1.1 THE SCOPE OF THERMODYNAMICS 1
1.2 DIMENSIONS AND UNITS 2
1.3 MEASURES OF AMOUNT OR SIZE 2
1.4 FORCE 3
1.5 TEMPERATURE 4
1.6 PRESSURE 6
1.7 WORK 8
1.8 ENERGY 9
1.9 HEAT 14
KEY NOTES 15
GLOSSARY AND EXPLANATIONS 17
CONCEPTUAL PROBLEMS 27
PROBLEMS 28
Chapter 2 The First Law and Other Basic Concepts 33
2.1 JOULE’S EXPERIMENTS 33
2.2 INTERNAL ENERGY 33
2.3 THE FIRST LAW OF THERMODYNAMICS 34
2.4 ENERGY BALANCE FOR CLOSED SYSTEMS 35
2.5 THERMODYNAMIC STATE AND STATE FUNCTIONS 37
2.6 EQUILIBRIUM 40
2.7 THE PHASE RULE 41
2.8 THE REVERSIBLE PROCESS 43
2.9 CONSTANT-V AND CONSTANT-P PROCESSES 48
2.10 ENTHALPY 49
2.11 HEAT CAPACITY 51
2.12 MASS AND ENERGY BALANCES FOR OPEN SYSTEMS 55
KEY NOTES 65
GLOSSARY AND EXPLANATIONS 68
CONCEPTUAL PROBLEMS 84
PROBLEMS 85
Chapter 3 Volumetric Properties of Pure Fluids 93
3.1 PVT BEHAVIOR OF PURE SUBSTANCES 93
3.2 VIRIAL EQUATIONS OF STATE 98
3.3 THE IDEAL GAS 101
3.4 APPLICATION OF THE VIRIAL EQUATIONS 113
3.5 CUBIC EQUATIONS OF STATE 117
3.6 GENERALIZED CORRELATIONS FOR GASES 126
3.7 GENERALIZED CORRELATIONS FOR LIQUIDS 134
KEY NOTES 136
GLOSSARY AND EXPLAINATIONS 140
CONCEPTUAL PROBLEMS 147
PROBLEMS 149
Chapter 4 Heat Effects 162
4.1 SENSIBLE HEAT EFFECTS 162
4.2 LATENT HEATS OF PURE SUBSTANCES 169
4.3 STANDARD HEAT OF REACTION 171
4.4 STANDARD HEAT OF FORMATION 173
4.5 STANDARD HEAT OF COMBUSTION 176
4.6 TEMPERATURE DEPENDENCE OF ΔH 176
4.7 HEAT EFFECTS OF INDUSTRIAL REACTIONS 179
KEY NOTES 187
GLOSSARY AND EXPLAINATIONS 187
CONCEPTUAL PROBLEMS 193
PROBLEMS 194
Chapter 5 The Second Law of Thermodynamics 202
5.1 STATEMENTS OF THE SECOND LAW 202
5.2 HEAT ENGINES 203
5.3 THERMODYNAMIC TEMPERATURE SCALES 206
5.4 ENTROPY 209
5.5 ENTROPY CHANGES OF AN IDEAL GAS 212
5.6 MATHEMATICAL STATEMENT OF THE SECOND LAW 215
5.7 ENTROPY BALANCE FOR OPEN SYSTEMS 217
5.8 CALCULATION OF IDEAL WORK 222
5.9 LOST WORK 226
5.10 THE THIRD LAW OF THERMODYNAMICS 229
KEY NOTES 230
GLOSSARY AND EXPLAINATIONS 231
CONCEPTUAL PROBLEMS 237
PROBLEMS 239
Chapter 6 Thermodynamic Properties of Fluids 247
6.1 PROPERTY RELATIONS FOR HOMOGENEOUS PHASES 247
6.2 RESIDUAL PROPERTIES 256
6.3 RESIDUAL PROPERTIES BY EQUATIONS OF STATE 263
6.4 TWO-PHASE SYSTEMS 268
6.5 THERMODYNAMIC DIAGRAMS 273
6.6 TABLES OF THERMODYNAMIC PROPERTIES 274
6.7 GENERALIZED PROPERTY CORRELATIONS FOR GASES 278
KEY NOTES 287
GLOSSARY AND EXPLAINATIONS 288
CONCEPTUAL PROBLEMS 293
PROBLEMS 295
Chapter 7 Applications of Thermodynamics to Flow Processes 308
7.1 DUCT FLOW OF COMPRESSIBLE FLUIDS 309
7.2 TURBINES (EXPANDERS) 321
7.3 COMPRESSION PROCESSES 327
KEY NOTES 333
GLOSSARY AND EXPLAINATIONS 335
CONCEPTUAL PROBLEMS 340
PROBLEMS 342
Chapter 8 Production of Power from Heat 352
8.1 THE STEAM POWER PLANT 353
8.2 INTERNAL-COMBUSTION ENGINES 363
8.3 JET ENGINES，ROCKET ENGINES AND RAMJET ENGINES 371
KEY NOTES 373
GLOSSARY AND EXPLAINATIONS 374
CONCEPTUAL PROBLEMS 377
PROBLEMS 379
Chapter 9 Refrigeration and Liquefaction 384
9.1 THE CARNOT REFRIGERATOR 384
9.2 THE VAPOR-COMPRESSION CYCLE 385
9.3 THE CHOICE OF REFRIGERANT 388
9.4 ABSORPTION REFRIGERATION 390
9.5 THE HEAT PUMP 392
9.6 LIQUEFACTION PROCESSES 393
KEY NOTES 398
GLOSSARY AND EXPLAINATIONS 399
CONCEPTUAL PROBLEMS 403
PROBLEMS 404
Chapter 10 Vapor/Liquid Equilibrium: Introduction 409
10.1 THE NATURE OF EQUILIBRIUM 409
10.2 THE PHASE RULE; DUHEM’S THEOREM 410
10.3 VLE: QUALITATIVE BEHAVIOR 412
10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM 414
10.5 VLE BY MODIFIED RAOULT’S LAW 423
10.6 VLE FROM K-VALUE CORRELATIONS 428
KEY NOTES 434
GLOSSARY AND EXPLAINATIONS 435
CONCEPTUAL PROBLEMS 442
PROBLEMS 444
Chapter 11 Solution Thermodynamics: Theory 452
11.1 FUNDAMENTAL PROPERTY RELATION 452
11.2 THE CHEMICAL POTENTIAL AND PHASE EQUILIBRIA 454
11.3 PARTIAL PROPERTIES 455
11.4 THE IDEAL-GAS MIXTURE MODEL 466
11.5 FUGACITY AND FUGACITY COEFFICIENT: PURE SPECIES 469
11.6 FUGACITY AND FUGACITY COEFFICIENT: SPECIES IN SOLUTION 475
11.7 GENERALIZED CORRELATIONS FOR THE FUGACITY COEFFICIENT 481
11.8 THE IDEAL-SOLUTION MODEL 485
11.9 EXCESS PROPERTIES 487
KEY NOTES 493
GLOSSARY AND EXPLAINATIONS 496
CONCEPTUAL PROBLEMS 501
PROBLEMS 502
Chapter 12 Solution Thermodynamics: Applications 512
12.1 LIQUID-PHASE PROPERTIES FROM VLE DATA 512
12.2 MODELS FOR THE EXCESS GIBBS ENERGY 527
12.3 PROPERTY CHANGES OF MIXING 530
12.4 HEAT EFFECTS OF MIXING PROCESSES 536
KEY NOTES 548
GLOSSARY AND EXPLAINATIONS 549
CONCEPTUAL PROBLEMS 553
PROBLEMS 555
Chapter 13 Chemical-Reaction Equilibria 567
13.1 THE REACTION COORDINATE 568
13.2 APPLICATION OF EQUILIBRIUM CRITERIA TO CHEMICAL REACTIONS 572
13.3 THE STANDARD GIBBS-ENERGY CHANGE AND THE EQUILIBRIUM
CONSTANT 573
13.4 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT 575
13.5 EVALUATION OF EQUILIBRIUM CONSTANTS 579
13.6 RELATION OF EQUILIBRIUM CONSTANTS TO COMPOSITION 581
13.7 EQUILIBRIUM CONVERSIONS FOR SINGLE REACTIONS 585
13.8 PHASE RULE AND DUHEM’S THEOREM FOR REACTING SYSTEMS 597
13.9 MULTIREACTION EQUILIBRIA 601
KEY NOTES 611
GLOSSARY AND EXPLAINATION 613
CONCEPTUAL PROBLEMS 617
PROBLEMS 619
Appendix A Conversion Factors and Values of the Gas Constant 630
Appendix B Properties of Pure Species 632
Appendix C Heat Capacities ad Property Changes of Formation 636
Appendix D Representative Computer Programs 641
参考文献 651
