化工热力学 英文版
出版时间： 2014年版
内容简介
本书适合48学时的教学计划。重点侧重于运用热力学基本原理与定律解决化工过程开发、设计与运行中的实际问题。教材内容主要涵盖：流体的P—V—T关系，流体的热力学性质，热力学基本定律及其应用，压缩、膨胀、蒸汽动力循环及制冷循环，化工过程的热力学分析，溶液的热力学及流体相平衡。
目录
Chapter 1Introduction1
1?1The Scope of Chemical Engineering Thermodynamics1
1?2System and Surroundings2
1?3The Chemical State and Fluid Properties2
1?4The First Law of Thermodynamics3
1?4?1The first law of thermodynamics for controlled mass system5
1?4?2The first law of thermodynamics for controlled volume system5
1?5The Second Law of Thermodynamics10
1?5?1The upper limit for the conversion of heat into work10
1?5?2Entropy13
1?5?3Mathematical statement of the second law14
Problems16Chapter 2Volumetric Properties of Fluids18
2?1p?V?T Behavior of Pure Substances18
2?2The Equations of State(EOS)of Fluid20
2?2?1The EOS of ideal gas21
2?2?2Virial equations of state21
2?3Cubic Equations of State24
2?3?1The van der Waals equation of state24
2?3?2The Redlich?Kwong(R?K)equation of state26
2?3?3The Soave?Redlich?Kwong(SRK)equation of state29
2?3?4The Peng?Robinson(P?R)equation of state30
2?3?5A generic cubic equation of state32
2?4Generalized Correlations of Gases32
2?4?1Theorem of corresponding states33
2?4?2Generalized cubic EOS33
2?4?3Two?parameter theorem of corresponding states35
2?4?4Three?parameter theorem of corresponding states37
2?4?5Generalized correlations of the second virial coefficient41
2?5Liquid & Liquid?like Roots of the Generic Cubic EOS43
2?6Generalized Correlations for Liquids45
Problems47Chapter 3Thermodynamic Properties of Fluids49
3?1Property Relations for Homogenous Phases49
3?2Calculations of Enthalpy and Entropy51
3?3Residual Properties52
3?4Residual Properties by EOS55
3?5Calculations of Liquid Enthalpy and Entropy57
3?6Generalized Property Correlations for Gases59
3?6?1Generalized compressibility factor Z for residual enthalpy and residual
entropy60
3?6?2Generalized second virial coefficient for residual enthalpy and residual
entropy61
3?7Thermodynamic Diagrams68
3?8Tables of Thermodynamic Properties69
3?9T?S Diagrams69
3?9?1Heating and cooling processes at isopiestic pressure72
3?9?2Throttling expansion processes72
3?9?3Isentropic expansion or compression processes72
3?10p?H Diagrams73
3?11H?S Diagrams74
Problems75Chapter 4Thermodynamic Properties of Mixtures77
4?1The Mixing Rules77
4?2The Calculations of Vm,mix and Zmix79
4?2?1Amagat’s law(part volume law)combined with Z graphs79
4?2?2EOS for a mixture of real gases80
4?3The Calculations of HR and SR86
4?3?1The calculations of HR and SR by EOS86
4?3?2The calculations of HR and SR by generalized correlation graphs88
Problems90Chapter 5Solution Thermodynamics92
5?1Property Relations for Open Systems and Chemical Potential93
5?2Partial Properties94
5?3Fugacity and Fugacity Coefficient99
5?3?1Fugacity calculations for pure gases100
5?3?2Fugacity calculations for pure liquids105
5?3?3Fugacity calculations for species in solution106
5?3?4Application of Microsoft Excel in the thermodynamic property calculations112
5?4The Ideal Solution and Standard State117
5?5Excess Properties and Property Change in Mixing119
5?5?1Excess properties119
5?5?2Property change in mixing120
5?5?3H?x graph122
5?6Activity and Activity Coefficient124
5?6?1The Wohl type equations127
5?6?2The gamma equation based on local composition131
5?6?3The UNIQUAC and UNIFAC model133
Problems136Chapter 6Phase Equilibrium139
6?1The Criterion of Phases Equilibrium139
6?2Vapor?Liquid Equilibrium140
6?2?1VLE under low pressures142
6?2?2VLE under moderate pressures152
6?2?3VLE under high pressures165
6?3Gas?Liquid Equilibrium167
6?4Liquid?Liquid Equilibrium169
6?4?1LLE phase diagrams170
6?4?2The stability of liquid solution171
6?4?3LLE calculations174
6?5Vapor?Liquid?Liquid Equilibrium (VLLE)175
Problems178Chapter 7Thermodynamics of Flow Process181
7?1Conservation of Mass182
7?2Conservation of Energy183
7?3Entropy Balance186
7?3?1Concept of entropy186
7?3?2Entropy balance187
7?4Processes Analyzed by Thermodynamics Methods190
7?4?1Fluid flowing190
7?4?2Compression process195
7?4?3Expansion process203
7?4?4Throttling process205
Problems209Chapter 8Thermodynamics Cycle212
8?1Carnot?Cycle and Its Anticlockwise Cycle213
8?2Rankine?Cycle & Steam Power Plant215
8?2?1Improving of the Carnot engine215
8?2?2Improving of the Rankine engine221
8?3Vapor Compression Refrigeration Cycle229
8?4Absorption Refrigeration231
8?5Heat Pump234
8?5?1A brief historical development of heat pumps235
8?5?2Vapor compression HP235
8?5?3Absorption heat pump238
Problems242Chapter 9Thermodynamic Analysis of Processes245
9?1Ideal Work245
9?1?1Non?flowing process245
9?1?2Steady?state flow process246
9?2Lost Work247
9?3Typical Problems248
9?3?1Tube flow248
9?3?2Heat transfer249
9?4 Energy Optimization250
Problems252Appendix255
Appendix AConversion Factors and Values of the Gas Constant255
Appendix BProperties of Pure Species256
Appendix CHeat Capacities and Property Changes of Formation258
Appendix DThe Lee/Kesler Generalized Correlation Tables263
Appendix ESteam Tables271
List of Symbols291
Selected Glossary in Chemical Engineering Thermodynamics with Chinese Translation293
References299
